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Gold(I)-Catalyzed Hydration of Allenes.

ABSTRACT: A gold(I) N-heterocyclic carbene complex catalyzes the intermolecular hydration of allenes to form allylic alcohols in modest yield with selective delivery of water to the terminal carbon atoms of the allenyl moiety.

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC2915905 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Gold(I)-Catalyzed Hydration of Allenes.

Zhang Zhibin Z   Du Lee Seong S   Fisher Aaron S AS   Widenhoefer Ross A RA  

Tetrahedron 20090201 9

A gold(I) N-heterocyclic carbene complex catalyzes the intermolecular hydration of allenes to form allylic alcohols in modest yield with selective delivery of water to the terminal carbon atoms of the allenyl moiety. ...[more]

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