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N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)-benzamide monohydrate.

ABSTRACT: In the title mol-ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl-pyridine group are respectively twisted by 67.9?(1) and 15.3?(3)° from the carbamoyl group defined by the plane of the O=C-N group of atoms. The water mol-ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant ?-? stacking inter-actions occur, with centroid-to-centroid separations in the range 3.567-3.681?(2)?Å.

SUBMITTER: Kobayashi M

PROVIDER: S-EPMC2959443 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)-benzamide monohydrate.

Kobayashi Masayuki M Masaoka Shigeyuki S Sakai Ken K

Acta crystallographica. Section E, Structure reports online 20080920 Pt 10

In the title mol-ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl-pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C-N group of atoms. The water mol-ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant π-π stacking inter-actions occur, with centroid-to-centroid separations in the range 3.567-3.681 (2) Å. ...[more]

PMID: 21201179

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