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Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II).

ABSTRACT: In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal-bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8?(3)°. In the crystal structure, short inter-molecular distances [3.627?(4)-3.671?(4)?Å] between the centroids of the six- and five-membered Cd-containing rings suggest the existence of ?-? inter-actions, which link the mol-ecules into stacks along the a axis.

SUBMITTER: Li JM

PROVIDER: S-EPMC2962234 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II).

Li Jin-Min JM

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal-bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short inter-molecular distances [3.627 (4)-3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the existence of π-π inter-actions, which link the mol-ecules into stacks along the a axis. ...[more]

PMID: 21203087

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