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Dichlorido[2,2'-(oxydimethyl-ene)dipyridine]zinc(II).

ABSTRACT: In the title complex, [ZnCl(2)(C(12)H(12)N(2)O)], the Zn(II) atom is coordinated in a distorted trigonal-bipyramidal geometry by two Cl atoms, and one O atom and two N atoms from the 2,2'-(oxydimethyl-ene)dipyridine ligand. In the complex, the two pyridine rings make a dihedral angle of 15.44?(14)°. There is a weak inter-molecular ?-? stacking inter-action between pyridine rings; the centroid-centroid distance is 3.8079?(17)?Å.

SUBMITTER: Li JM 

PROVIDER: S-EPMC2959519 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Dichlorido[2,2'-(oxydimethyl-ene)dipyridine]zinc(II).

Li Jin Min JM  

Acta crystallographica. Section E, Structure reports online 20081031 Pt 11

In the title complex, [ZnCl(2)(C(12)H(12)N(2)O)], the Zn(II) atom is coordinated in a distorted trigonal-bipyramidal geometry by two Cl atoms, and one O atom and two N atoms from the 2,2'-(oxydimethyl-ene)dipyridine ligand. In the complex, the two pyridine rings make a dihedral angle of 15.44 (14)°. There is a weak inter-molecular π-π stacking inter-action between pyridine rings; the centroid-centroid distance is 3.8079 (17) Å. ...[more]

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