Ontology highlight
ABSTRACT:
SUBMITTER: Block M
PROVIDER: S-EPMC2959718 | biostudies-literature | 2008 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20081015 Pt 11
In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis-(dimethyl-phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](-) (cod = 1,5-cyclo-octa-diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclo-octa-diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter-actions. ...[more]