Unknown

Dataset Information

0

Bis[1,2-bis-(dimethyl-phosphino)ethane-?P,P']rhodium(I) dichlorido[(1,2,5,6-?)-1,5-cyclo-octa-diene]rhodium(I).

ABSTRACT: In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis-(dimethyl-phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](-) (cod = 1,5-cyclo-octa-diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic ?-bonds of the cyclo-octa-diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter-actions.

SUBMITTER: Block M 

PROVIDER: S-EPMC2959718 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[1,2-bis-(dimethyl-phosphino)ethane-κP,P']rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclo-octa-diene]rhodium(I).

Block Michael M   Gómez-Ruiz Santiago S   Steinborn Dirk D  

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis-(dimethyl-phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](-) (cod = 1,5-cyclo-octa-diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclo-octa-diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter-actions. ...[more]

Similar Datasets

Unknown Dichlorido(?-cyclo-octa-1,5-diene)bis-(triphenyl-phosphine)osmium(II).
| S-EPMC2970349 | biostudies-literature
Unknown Bis(acrylonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II).
| S-EPMC3201466 | biostudies-literature
Unknown [(1,2,5,6-?)-Cyclo-octa-1,5-diene]bis-(4-methyl-phen-yl)platinum(II).
| S-EPMC3050351 | biostudies-literature
Unknown Crystal structure of chlorido-bis-[(1,2,5,6-?)-cyclo-octa-1,5-diene]iridium(I).
| S-EPMC5290581 | biostudies-literature
Unknown Dichlorido(?-cyclo-octa-1,5-diene)bis-(propane-nitrile-?N)ruthenium(II).
| S-EPMC3201259 | biostudies-literature
Unknown [(1,2,5,6-?)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate.
| S-EPMC3238752 | biostudies-literature
Unknown Bromido[(1,2,5,6-?)-cyclo-octa-1,5-diene]methyl-platinum(II).
| S-EPMC2980049 | biostudies-literature
Unknown Bis(acetonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate.
| S-EPMC3212168 | biostudies-literature
Unknown Chloridocyclo-hexyl[(1,2,5,6-η)-cyclo-octa-1,5-diene]platinum(II).
| S-EPMC2971967 | biostudies-literature
Unknown (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane-?P,P'}(?-cyclo-octa-1,5-diene)rhodium(I) tetra-fluorido-borate.
| S-EPMC2979608 | biostudies-literature