Unknown

Dataset Information

0

Bis[1,2-bis-(dimethyl-phosphino)ethane-?P,P']rhodium(I) dichlorido[(1,2,5,6-?)-1,5-cyclo-octa-diene]rhodium(I).


ABSTRACT: In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis-(dimethyl-phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](-) (cod = 1,5-cyclo-octa-diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic ?-bonds of the cyclo-octa-diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter-actions.

SUBMITTER: Block M 

PROVIDER: S-EPMC2959718 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

altmetric image

Publications

Bis[1,2-bis-(dimethyl-phosphino)ethane-κP,P']rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclo-octa-diene]rhodium(I).

Block Michael M   Gómez-Ruiz Santiago S   Steinborn Dirk D  

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11


In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis-(dimethyl-phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](-) (cod = 1,5-cyclo-octa-diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclo-octa-diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter-actions. ...[more]

Similar Datasets

| S-EPMC3008980 | biostudies-literature
| S-EPMC3274931 | biostudies-literature
| S-EPMC5290581 | biostudies-literature
| S-EPMC2960239 | biostudies-literature
| S-EPMC2971967 | biostudies-literature
| S-EPMC11299652 | biostudies-literature
| S-EPMC9462365 | biostudies-literature
| S-EPMC3238752 | biostudies-literature
| S-EPMC2970349 | biostudies-literature
| S-EPMC3201466 | biostudies-literature