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Cis-Bis(acetonitrile-?N)bis-(2,2'-bipyridine-?N,N')ruthenium(II) tetra-fluoridoborate.

ABSTRACT: In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by the N atoms of the two 2,2'-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol-ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86?(12) and 10.12?(14)°. In the crystal, the cations and anions are linked by C-H?F hydrogen bonds into a three-dimensional network.

SUBMITTER: Wang Y

PROVIDER: S-EPMC3254331 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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cis-Bis(acetonitrile-κN)bis-(2,2'-bipyridine-κN,N')ruthenium(II) tetra-fluoridoborate.

Wang Ying Y Xu Feng F Huang Wei W

Acta crystallographica. Section E, Structure reports online 20111221 Pt 1

In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by the N atoms of the two 2,2'-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol-ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are linked by C-H⋯F hydrogen bonds into a three-dimensional network. ...[more]

PMID: 22259364

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