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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-?(2)N,O}cobalt(II).

ABSTRACT: The complete mol-ecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetra-hedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1?(6)°.

SUBMITTER: Yu H 

PROVIDER: S-EPMC3515158 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}cobalt(II).

Yu Hong H   Chen Zhu-Jun ZJ   Jin Yue-Bao YB   Chang Yong-Kang YK   Lei Ke-Wei KW  

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11

The complete mol-ecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetra-hedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°. ...[more]

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