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Poly[?-azido-(?(3)-nicotinato N-oxide)zinc(II)].

ABSTRACT: The title compound, [Zn(C(6)H(4)NO(3))(N(3))], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide. The Zn atom is five coordinated by two azide anions and three nicotinate N-oxide ligands. Each nicotinate N-oxide bridges three Zn atoms, whereas the azide bridges two Zn atoms, resulting in the formation of a two-dimensional metal-organic polymer developing parallel to (100).

SUBMITTER: Xin CW

PROVIDER: S-EPMC2960059 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Poly[μ-azido-(μ(3)-nicotinato N-oxide)zinc(II)].

Xin Chun-Wei CW Liu Fu-Chen FC

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

The title compound, [Zn(C(6)H(4)NO(3))(N(3))], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide. The Zn atom is five coordinated by two azide anions and three nicotinate N-oxide ligands. Each nicotinate N-oxide bridges three Zn atoms, whereas the azide bridges two Zn atoms, resulting in the formation of a two-dimensional metal-organic polymer developing parallel to (100). ...[more]

PMID: 21581219

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