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Bis(ethyl-enedithio)tetra-thia-fulvalenium-tetra-chloridocobaltate(II) (3/2).

ABSTRACT: The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis-(ethyl-enedithio)tetra-thia-fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra-hedral [CoCl(4)](2-) anions. One of the BEDT-TTF mol-ecules is generated by inversion. There are short S?S contacts between the stacks in the a direction and short C-H?Cl contacts between the radical cations and the anions.

SUBMITTER: Zhao F

PROVIDER: S-EPMC2960064 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Bis(ethyl-enedithio)tetra-thia-fulvalenium-tetra-chloridocobaltate(II) (3/2).

Zhao Fuqi F Li Ping P Zhu Xiaohui X Dong Lihua L

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis-(ethyl-enedithio)tetra-thia-fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra-hedral [CoCl(4)](2-) anions. One of the BEDT-TTF mol-ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C-H⋯Cl contacts between the radical cations and the anions. ...[more]

PMID: 21581134

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