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[Malonato(2-)-?O,O']bis-(1,10-phenanthroline-?N,N')zinc(II) penta-hydrate.

ABSTRACT: In the title complex, [Zn(C(3)H(2)O(4))(C(12)H(8)N(2))(2)]·5H(2)O, the Zn(II) cation displays a distorted octa-hedral geometry, being coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from different carboxyl-ate groups of the chelating malonate dianion. In the crystal, the complexes are linked into a three-dimensional supra-molecular network by both O-H?O hydrogen-bonding inter-actions between water mol-ecules and the uncoordinated carboxyl-ate O atoms of neighboring mol-ecules, and aromatic ?-? stacking inter-actions between neighboring phenanthroline rings with centroid-centroid distances of 3.4654?(17) and 3.697?(2)?Å.

SUBMITTER: Chen YM 

PROVIDER: S-EPMC3050196 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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[Malonato(2-)-κO,O']bis-(1,10-phenanthroline-κN,N')zinc(II) penta-hydrate.

Chen Yan-Min YM   Xie Qing-Fan QF  

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title complex, [Zn(C(3)H(2)O(4))(C(12)H(8)N(2))(2)]·5H(2)O, the Zn(II) cation displays a distorted octa-hedral geometry, being coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from different carboxyl-ate groups of the chelating malonate dianion. In the crystal, the complexes are linked into a three-dimensional supra-molecular network by both O-H⋯O hydrogen-bonding inter-actions between water mol-ecules and the uncoordinated carboxyl-ate O atoms of neighbori  ...[more]

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