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Trans-Bis(4,7-diphenyl-1,10-phenanthroline-?N,N')bis-(nitrato-?O,O')zinc(II).

ABSTRACT: The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn-O interactions [2.4926?(15) and 2.6673?(15)?Å] can be considered as weakly bonding and the nitrate ions share the same C(2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion.

SUBMITTER: Fernandes JA

PROVIDER: S-EPMC3011604 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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trans-Bis(4,7-diphenyl-1,10-phenanthroline-κN,N')bis-(nitrato-κO,O')zinc(II).

Fernandes José A JA Almeida Paz Filipe A FA Liu Feng-Yi FY Cunha-Silva Luís L Carlos Luís D LD Rocha João J

Acta crystallographica. Section E, Structure reports online 20101120 Pt 12

The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn-O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C(2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion. ...[more]

PMID: 21589287

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