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Catena-Poly[[[diaqua-copper(II)]-bis-[?-1,1'-(butane-1,4-di-yl)diimidazole-?N:N]] dinitrate].

ABSTRACT: In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O-H?O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions.

SUBMITTER: Wang XF

PROVIDER: S-EPMC2960687 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[[diaqua-copper(II)]-bis-[μ-1,1'-(butane-1,4-di-yl)diimidazole-κN:N]] dinitrate].

Wang Xiao-Feng XF Wang Jin-Feng JF Liu Xiao-Yang XY

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9

In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O-H⋯O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions. ...[more]

PMID: 21201651

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catena-Poly[[dichloridozinc(II)]-?-1,1'-(butane-1,4-di-yl)diimidazole-?N:N].

Project description:The title compound, [ZnCl(2)(C(10)H(14)N(4))](n), is a coordination polymer consisting of zigzag chains propagating in [001], in which the metal cation exhibits a distorted tetrahedral ZnCl(2)N(2) coordination. Adjacent chains are linked by inter-molecular C-H?Cl hydrogen bonds, forming a three-dimensional supra-molecular network.

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