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Catena-Poly[[dichloridozinc(II)]-?-[1,1'-(butane-1,4-di-yl)diimidazole-?N:N]].


ABSTRACT: The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are located around two sets of inversion centers and bridge Zn(II) ions, forming a zigzag polymeric chain. C-H?Cl hydrogen bonding results in the formation of a three-dimensional supra-molecular network.

SUBMITTER: Lin J 

PROVIDER: S-EPMC3011725 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridozinc(II)]-μ-[1,1'-(butane-1,4-di-yl)diimidazole-κN:N]].

Lin Jing J   Cai Wen-Lian WL   Li Xi-Zhong XZ   Huang Sen-Ke SK  

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12


The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are located around two sets of inversion centers and bridge Zn(II) ions, forming a zigzag polymeric chain. C-H⋯Cl  ...[more]

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