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Poly[[[diaqua-cobalt(II)]-bis-[μ-1,1'-(butane-1,4-di-yl)diimidazole-κN:N]] dichloride tetra-hydrate].

ABSTRACT: In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1'-butane-1,4-diyl-diimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octa-hedral environment by four N atoms from four different ligands and by two O atoms from the water mol-ecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water mol-ecules via O-H⋯Cl and O-H⋯O hydrogen bonds, generating a three-dimensional supra-molecular structure.

SUBMITTER: Su Y

PROVIDER: S-EPMC2968895 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Poly[[[diaqua-cobalt(II)]-bis-[μ-1,1'-(butane-1,4-di-yl)diimidazole-κN:N]] dichloride tetra-hydrate].

Su Yu Y Hou Yan-Jun YJ Sun Zhi-Zhong ZZ Hou Guang-Feng GF Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20090306 Pt 4

In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1'-butane-1,4-diyl-diimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octa-hedral environment by four N atoms from four different ligands and by two O atoms from the water mol-ecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water mol-ecules ...[more]

PMID: 21582325

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Poly[[μ(2)-2,2'-diethyl-1,1'-(butane-1,4-di-yl)diimidazole-κN:N](μ(2)-5-hydroxy-isophthalato-κO:O)zinc].

Project description:In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(14)H(22)N(4))](n), the Zn(II) cation is coordinated by an O(2)N(2) donor set in a distorted tetra-hedral geometry. The Zn(II) ions are linked by μ(2)-OH-bdc (OH-H(2)bdc = 5-hy-droxy-isophthalic acid) and bbie ligands [bbie = 2,2'-diethyl-1,1'-(butane-1,4-di-yl)diimidazole], forming a two-dimensional layer parallel to the ab plane. The layers are further connected through intermolecular C-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure. In the bbie ligand, the two C atoms in the ethyl group are each disordered over two positions with a site-occupancy ratio of 0.69:0.31.

| S-EPMC3246914 | biostudies-literature

Poly[[[diaqua-cobalt(II)]-bis-[?(2)-1,1'-(butane-1,4-di-yl)diimidazole-?N:N]] dinitrate].

Project description:In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Co(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. The Co(II) atoms are bridged by ligands, generating a two-dimensional (4,4)-network. Adjacent fishnet planes are linked to the nitrate anions via O-H?O hydrogen bonds, forming a three-dimensional supra-molecular structure.

| S-EPMC2968530 | biostudies-other

Poly[μ-aqua-[μ-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dicadmium(II)].

Project description:In the title compound, [Cd(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n), the coordination polyhedron around each Cd(II) ion is a distorted CdNO(5) octa-hedron. The water O atom has site symmetry 2 and the complete 1,1'-(butane-1,4-di-yl)diimidazole (L) ligand is generated by inversion. The naphthalene-1,4-dicarboxyl-ate and L ligands bridge the metal centres, forming a three-dimensional framework, which is consolidated by O-H⋯O hydrogen bonds.

| S-EPMC2960000 | biostudies-literature

catena-Poly[[[diaqua-copper(II)]-bis-[?-1,1'-(butane-1,4-di-yl)diimidazole-?N:N]] dinitrate].

Project description:In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O-H?O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions.

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Poly[μ(2)-aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dimanganese(II)].

Project description:In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral. The water mol-ecule and the L ligand are situated across a twofold rotation axis. The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O-H⋯O hydrogen bonds are observed within the network.

| S-EPMC2960017 | biostudies-literature

3,3'-(Butane-1,4-di-yl)diimidazole-1,1'-diium bis-(triiodide).

Project description:The cations and anions of the salt, C(10)H(16)N(4) (2+)·2I(3) (-), are linked by N-H⋯I hydrogen bonds and π-π stacking inter-actions(with interplanar distances of 3.575 and 3.528 Å) into a three-dimensional supra-molecular network. The asymmetric unit contains two anions and two half-cations; each cation is centrosymmetric.

| S-EPMC2962153 | biostudies-literature

Poly[[[?-1,1'-(butane-1,4-di-yl)diimidazole-?N:N](?-cyclo-hexane-1,4-dicarboxyl-ato-?O,O:O,O)nickel(II)] 0.25-hydrate].

Project description:In the title coordination polymer, {[Ni(C(8)H(10)O(4))(C(10)H(14)N(4))]·0.25H(2)O}(n), the coordination of the Ni(II) ion is distorted octa-hedral. The 1,1'-(butane-1,4-di-yl)diimidazole ligand and the cyclo-hexane-1,4-dicarboxyl-ate dianion bridge metal centres, forming a two-dimensional (4,4) network. The network is consolidated by O-H?O hydrogen bonds between the statistically occupied water molecules and O atoms of the two carboxylate groups.

| S-EPMC2968582 | biostudies-literature

catena-Poly[[dichloridozinc(II)]-?-[1,1'-(butane-1,4-di-yl)diimidazole-?N:N]].

Project description:The title one-dimensional coordination polymer, [ZnCl(2)(C(10)H(14)N(4))](n), was synthesized by hydro-thermal methods from ZnCl(2) and 1,1'-(butane-1,4-di-yl)diimidazole. The Zn atom is coordinated by two chloride ions and two N atoms from two symmetry-independent organic ligands and shows a distorted tetra-hedral coordination geometry. The 1,1'-(butane-1,4-di-yl)diimidazole ligands are located around two sets of inversion centers and bridge Zn(II) ions, forming a zigzag polymeric chain. C-H?Cl hydrogen bonding results in the formation of a three-dimensional supra-molecular network.

| S-EPMC3011725 | biostudies-literature

catena-Poly[[dichloridozinc(II)]-?-1,1'-(butane-1,4-di-yl)diimidazole-?N:N].

Project description:The title compound, [ZnCl(2)(C(10)H(14)N(4))](n), is a coordination polymer consisting of zigzag chains propagating in [001], in which the metal cation exhibits a distorted tetrahedral ZnCl(2)N(2) coordination. Adjacent chains are linked by inter-molecular C-H?Cl hydrogen bonds, forming a three-dimensional supra-molecular network.

| S-EPMC3006791 | biostudies-literature

1,1'-(Butane-1,4-di-yl)diimidazole-3,3'-diium tetra-chloridozincate(II) dihydrate.

Project description:In the title compound, (C(10)H(16)N(4))[ZnCl(4)]·2H(2)O, the cation lies abouton a center of inversion and the anion about a twofold rotation axis. The Zn(II) atom is four-coordinate in a tetra-hedral environment. The cations, anions and water mol-ecules are linked by N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds into a two-dimensional network.

| S-EPMC2961250 | biostudies-literature

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