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Aqua-chloridodimethyl-phenyltin(IV)-15-crown-5 (2/1).

ABSTRACT: The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol-ecule forms two hydrogen bonds to the 15-crown-5?mol-ecule, which is disordered about a center of inversion.

SUBMITTER: Armaghan M

PROVIDER: S-EPMC2961118 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Aqua-chloridodimethyl-phenyltin(IV)-15-crown-5 (2/1).

Armaghan Mahsa M Amini Mostafa M MM Azadmehr Amirreza A Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080426 Pt 5

The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol-ecule forms two hydrogen bonds to the 15-crown-5 mol-ecule, which is disordered about a center of inversion. ...[more]

PMID: 21202247

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