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Tris[2-(deuteriomethyl-sulfan-yl)-phen-yl]-phosphine deuteriochloro-form 0.125-solvate.

ABSTRACT: The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol-ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro-form solvate. The solvent mol-ecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry.

SUBMITTER: Wong RC

PROVIDER: S-EPMC2961173 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Tris[2-(deuteriomethyl-sulfan-yl)-phen-yl]-phosphine deuteriochloro-form 0.125-solvate.

Wong Richard Chee Seng RC Ooi Mei Lee ML Sakurai Hidehiro H Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol-ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro-form solvate. The solvent mol-ecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry. ...[more]

PMID: 21202381

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