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Chlorido[tris-(3-fluoro-phen-yl)phosphine]gold(I).

ABSTRACT: In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P-Au-Cl unit is nearly linear, with an angle of 178.13?(5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7?(3), 84.4?(3) and 77.4?(3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591?(11):0.409?(11) and 0.730?(12):0.270?(12). In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular C-H?Cl and C-H?F hydrogen bonds.

SUBMITTER: Shawkataly OB

PROVIDER: S-EPMC2983311 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Chlorido[tris-(3-fluoro-phen-yl)phosphine]gold(I).

Shawkataly Omar Bin OB Tariq Abu A Ghani Syed Sauban SS Yeap Chin Sing CS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10

In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P-Au-Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591 (11):0.409 (11) and 0.730 (12):0.270 (12). In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular C-H⋯Cl and C-H⋯F hydr ...[more]

PMID: 21587375

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