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Bis-(N,N'-diphenyl-thio-urea)iodido-copper(I) monohydrate.

ABSTRACT: In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu-S 2.2282?(16), 2.2377?(15)?Å] from two N,N'-diphenyl-thio-urea ligands and one iodide ion [Cu-I 2.5170?(11)?Å] in a trigonal planar geometry. The uncoordinated water mol-ecules are involved in N-H?O hydrogen-bonding [N?O 2.947?(5), 3.055?(5)?Å], which link the mol-ecules into chains extended in the [101] direction. These chains are further paired by weak inter-molecular O-H?S hydrogen bonds [O?S 3.490?(4)?Å].

SUBMITTER: Jia L

PROVIDER: S-EPMC2961451 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Bis-(N,N'-diphenyl-thio-urea)iodido-copper(I) monohydrate.

Jia Li L Kong Lingqian L Li Dacheng D

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu-S 2.2282 (16), 2.2377 (15) Å] from two N,N'-diphenyl-thio-urea ligands and one iodide ion [Cu-I 2.5170 (11) Å] in a trigonal planar geometry. The uncoordinated water mol-ecules are involved in N-H⋯O hydrogen-bonding [N⋯O 2.947 (5), 3.055 (5) Å], which link the mol-ecules into chains extended in the [101] direction. These chains are further paired by weak inter-molecular O-H⋯S hydrogen bonds [ ...[more]

PMID: 21202456

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