Browse
Submit Data
Databases
API
Help

Dataset Information

17 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).

ABSTRACT: The coordination geometry of the Cu atom in the title compound, [CuI(C(7)H(8)N(2)S)(C(18)H(15)P)(2)], is distorted tetra-hedral; it is coordinated by two triphenyl-phosphine P atoms, one S atom from N-phenyl-thio-urea (ptu) and one I atom. The crystal structure is stabilized by intra- and inter-molecular N-H?I and N-H?S inter-actions.

SUBMITTER: Nimthong R

PROVIDER: S-EPMC2961665 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).

Nimthong Ruthairat R Pakawatchai Chaveng C Saithong Saowanit S Charmant Jonathan P H JP

Acta crystallographica. Section E, Structure reports online 20080628 Pt 7

The coordination geometry of the Cu atom in the title compound, [CuI(C(7)H(8)N(2)S)(C(18)H(15)P)(2)], is distorted tetra-hedral; it is coordinated by two triphenyl-phosphine P atoms, one S atom from N-phenyl-thio-urea (ptu) and one I atom. The crystal structure is stabilized by intra- and inter-molecular N-H⋯I and N-H⋯S inter-actions. ...[more]

PMID: 21202821

Similar Datasets

Bis-(N,N'-diphenyl-thio-urea)iodido-copper(I) monohydrate.

Project description:In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu-S 2.2282?(16), 2.2377?(15)?Å] from two N,N'-diphenyl-thio-urea ligands and one iodide ion [Cu-I 2.5170?(11)?Å] in a trigonal planar geometry. The uncoordinated water mol-ecules are involved in N-H?O hydrogen-bonding [N?O 2.947?(5), 3.055?(5)?Å], which link the mol-ecules into chains extended in the [101] direction. These chains are further paired by weak inter-molecular O-H?S hydrogen bonds [O?S 3.490?(4)?Å].

| S-EPMC2961451 | biostudies-literature

Chlorido(1,3-dimethyl-thio-urea-?S)bis-(triphenyl-phosphine-?P)copper(I) acetonitrile hemisolvate.

Project description:The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl-thio-urea (dmtu) and triphenyl-phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra-hedral environment formed by two P atoms from triphenyl-phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol-ecules exhibit intra- and inter-molecular N-H?Cl inter-actions.

| S-EPMC2977114 | biostudies-other

?-Oxalato-bis-[bis-(triphenyl-phosphine)copper(I)] dichloro-methane disolvate.

Project description:The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57?(5)° and P-Cu-P = 125.72?(2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

| S-EPMC3569214 | biostudies-literature

Bis(dicyclo-hexyl-phenyl-phosphine)iodido-silver(I) pyridine monosolvate.

Project description:The structure of the title compound, [AgI(C(18)H(27)P)(2)]·C(5)H(5)N, shows a trigonal-planar coordinated Ag(I) atom within a distorted IAgP(2) donor set. The pyridine solvent mol-ecule is only associated with the complex via very weak inter-molecular C-H?N inter-actions.

| S-EPMC2971293 | biostudies-literature

Aqua-bis(triphenyl-phosphine-?P)copper(I) tetra-fluoridoborate.

Project description:In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl-phosphine ligands and one water mol-ecule in a distorted trigonal geometry. In the BF(4) (-) anion, three F atoms are disordered over two sites around the B-F bond, the site-occupancy ratio being 0.67?(6):0.33?(6). The Cu?F distance of 2.602?(5)?Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter-action. O-H?F and weak C-H?F hydrogen bonding is present in the crystal structure.

| S-EPMC2977191 | biostudies-literature

Bis(pyridine-?N)bis-(triphenyl-phosphine-?P)copper(I) tetra-fluoridoborate.

Project description:The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](-) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C-H?F inter-actions apparent. The P(2)CuN(2) coordination geometry is pseudo-tetra-hedral, with P-Cu-P and N-Cu-N angles of 116.02?(6) and 101.5?(2)°, respectively.

| S-EPMC2961139 | biostudies-literature

(Sulfasalazinato-?O)bis-(triphenyl-phosphine-?P)copper(I).

Project description:The title mixed-ligand copper(I) complex, [Cu(C(18)H(13)N(4)O(5)S)(C(18)H(15)P)(2)], was synthesized via solvothermal reaction of [Cu(PPh(3))(2)(MeCN)(2)]ClO(4) and sulfasalazine [systematic name: 2-hydr-oxy-5-(2-{4-[(2-pyridylamino)sulfon-yl]phen-yl}diazen-yl)benzoic acid]. The mononuclear complex displays a trigonal coordination geometry for the Cu(I) atom, which is surrounded by two P-atom donors from two different PPh(3) ligands and one O-atom donor from the monodentate carboxyl-ate group of the sulfasalazinate ligand. The latter ligand is found in a zwitterionic form, with a deprotonated amine N atom and a protonated pyridine N atom. Such a feature was previously described for free sulfasalazine. The crystal structure is stabilized by C-H?O, C-H?N, N-H?N and O-H?O hydrogen bonds.

| S-EPMC2979139 | biostudies-other

Iodido[1-(propan-2-yl-idene)thio-semi-carbazide-?S]bis-(triphenyl-phosphane-?P)copper(I).

Project description:In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra-hedral coordination geometry involving two P atoms of two triphenyl-phosphane mol-ecules, one S atom of a 1-(propan-2-yl-idene)thio-semicarbazide mol-ecule and one iodide ion. In the crystal, C-H?? inter-actions [C-H?centroid distances = 3.443?(3) and 3.788?(3)?Å] and N-H?S hydrogen bonds form layers parallel to (100). An intra-molecular N-H?I hydrogen bond is also observed.

| S-EPMC3515154 | biostudies-other

(1-Acetyl-thio-urea-?S)bromido-bis(triphenyl-phosphane-?P)silver(I).

Project description:In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the Ag(I) ion is in a distorted tetra-hedral geometry coordinated by two P atoms from two triphenyl-phosphane ligands, one S atom of an acetyl-thio-urea ligand and one bromide ligand. There are intra-molecular N-H?Br and N-H?O hydrogen bonds present. In the crystal, pairs of N-H?S hydrogen bonds involving thio-urea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an inter-molecular P?P distance of 6.4586?(17)?Å.

| S-EPMC3588756 | biostudies-literature

catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

Project description:In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120?(5)?Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

| S-EPMC3201507 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data