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Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).

ABSTRACT: The coordination geometry of the Cu atom in the title compound, [CuI(C(7)H(8)N(2)S)(C(18)H(15)P)(2)], is distorted tetra-hedral; it is coordinated by two triphenyl-phosphine P atoms, one S atom from N-phenyl-thio-urea (ptu) and one I atom. The crystal structure is stabilized by intra- and inter-molecular N-H?I and N-H?S inter-actions.

SUBMITTER: Nimthong R

PROVIDER: S-EPMC2961665 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).

Nimthong Ruthairat R Pakawatchai Chaveng C Saithong Saowanit S Charmant Jonathan P H JP

Acta crystallographica. Section E, Structure reports online 20080628 Pt 7

The coordination geometry of the Cu atom in the title compound, [CuI(C(7)H(8)N(2)S)(C(18)H(15)P)(2)], is distorted tetra-hedral; it is coordinated by two triphenyl-phosphine P atoms, one S atom from N-phenyl-thio-urea (ptu) and one I atom. The crystal structure is stabilized by intra- and inter-molecular N-H⋯I and N-H⋯S inter-actions. ...[more]

PMID: 21202821

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catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

Project description:In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120?(5)?Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

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