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Tetra-n-butyl-ammonium iodido(pyrrolidine-1-carbodithio-ato-?S,S')(tris-tert-butoxy-silanethiol-ato-?S)cadmate(II).

ABSTRACT: In the anion of the title compound, (C(16)H(36)N)[Cd(C(5)H(8)NS(2))(C(12)H(27)O(3)SSi)I], the Cd atom is four-coordinated by S,S'-chelating dithio-carbamate, S-donating silanethiol-ate and iodide ligands in a distorted tetrahedral environment . Inter-molecular C-H? S and C-H?I inter-actions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.

SUBMITTER: Kropidlowska A 

PROVIDER: S-EPMC2961457 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Tetra-n-butyl-ammonium iodido(pyrrolidine-1-carbodithio-ato-κS,S')(tris-tert-butoxy-silanethiol-ato-κS)cadmate(II).

Kropidłowska Anna A   Chojnacki Jarosław J   Becker Barbara B  

Acta crystallographica. Section E, Structure reports online 20080521 Pt 6

In the anion of the title compound, (C(16)H(36)N)[Cd(C(5)H(8)NS(2))(C(12)H(27)O(3)SSi)I], the Cd atom is four-coordinated by S,S'-chelating dithio-carbamate, S-donating silanethiol-ate and iodide ligands in a distorted tetrahedral environment . Inter-molecular C-H⋯ S and C-H⋯I inter-actions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35. ...[more]

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