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Bis(tetra-butyl-ammonium) bis-(3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ato-?S,S')cadmate(II) 0.25-hydrate.

ABSTRACT: The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra-butyl-ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2-) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ate (dtcroc) group forming a distorted tetra-hedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10?(8)°. The crystal packing is stabilized by weak C-H?O and C-H?S cation-anion hydrogen-bond inter-actions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589?(11):0.411?(11) and 0.796?(12):0.204?(12).

SUBMITTER: Chen HY 

PROVIDER: S-EPMC3050421 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Bis(tetra-butyl-ammonium) bis-(3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ato-κS,S')cadmate(II) 0.25-hydrate.

Chen Hong-Yu HY   Xia Guang-Ming GM   Zhang Zhen-Wei ZW   Li Ping P  

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra-butyl-ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2-) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ate (dtcroc) group forming a distorted tetra-hedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°  ...[more]

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