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Di-μ-oxido-bis-({(R)-(-)-2-[1-(2-amino-propyl-imino)eth-yl]-1-naphtholato-κN,N',O}oxidovanadium(V)).

ABSTRACT: In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa-hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N-H⋯O, C-H⋯O and C-H⋯π hydrogen bonds, and π-π inter-actions.

SUBMITTER: Romanowski G

PROVIDER: S-EPMC2961648 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Di-μ-oxido-bis-({(R)-(-)-2-[1-(2-amino-propyl-imino)eth-yl]-1-naphtholato-κN,N',O}oxidovanadium(V)).

Romanowski Grzegorz G Sikorski Artur A Wojtczak Andrzej A

Acta crystallographica. Section E, Structure reports online 20080621 Pt 7

In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa-hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure ...[more]

PMID: 21202800

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