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Di-?-oxido-bis-[(4-formyl-2-methoxy-phenolato-?O)oxido(1,10-phenan-throline-?N,N')vanadium(V)].

ABSTRACT: The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two ?(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H?O hydrogen bonds connect the mol-ecules into a three-dimensional network.

SUBMITTER: Guo Z

PROVIDER: S-EPMC2970134 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Di-μ-oxido-bis-[(4-formyl-2-methoxy-phenolato-κO)oxido(1,10-phenan-throline-κN,N')vanadium(V)].

Guo Zhenghua Z Li Lianzhi L Xu Tao T Li Jinghong J

Acta crystallographica. Section E, Structure reports online 20090822 Pt 9

The title complex, [V(2)(C(8)H(7)O(3))(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric dimer formed by two V(V) complex units bridged by two μ(2)-oxido groups. The V(V) atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds connect the mol-ecules into a three-dimensional network. ...[more]

PMID: 21577458

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