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Diazido-bis(2,2'-biimidazole)iron(II).

ABSTRACT: In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa-hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355?(2)?Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol-ecule.

SUBMITTER: Hao L

PROVIDER: S-EPMC2961650 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Diazido-bis(2,2'-biimidazole)iron(II).

Hao Lujiang L Mu Chunhua C Kong Binbin B

Acta crystallographica. Section E, Structure reports online 20080625 Pt 7

In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa-hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol-ecule. ...[more]

PMID: 21202805

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