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Diazido-(2,2'-bipyrid-yl)dimethanol-nickel(II).

ABSTRACT: The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa-hedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hy-droxy groups form intra-molecular O-H?(N,N) hydrogen bonds with the azide ligands.

SUBMITTER: Li HG

PROVIDER: S-EPMC3009301 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Diazido-(2,2'-bipyrid-yl)dimethanol-nickel(II).

Li Hong-Gang HG Li Shao-Ying SY Shao Li-Jun LJ

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa-hedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hy-droxy groups form intra-molecular O-H⋯(N,N) hydrogen bonds with the azide ligands. ...[more]

PMID: 21588795

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