Bis(?-2,2'-biimidazole-?N:N)bis-[aqua-copper(I)] sulfate.

ABSTRACT: In the structure of the title compound, [Cu(2)(C(6)H(6)N(4))(2)(H(2)O)(2)]SO(4), the asymmetric unit contains half each of two 2,2'-diimidazole ligands, one Cu(+) cation, one water mol-ecule and half of a sulfate anion (2 symmetry). The dinuclear complex is completed through a twofold rotation axis, leading to a twisted ten-membered ring mol-ecule. The dihedral angle between the two symmetry-related 2,2'-diimidazole ligands is 23.6?(1)°. The copper centre is coordinated by two N atoms of two symmetry-related 2,2'-diimidazole ligands in an almost linear fashion. The water mol-ecule exhibits a weak coordination to Cu(+) with a more remote distance of 2.591?(2)?Å. The distance between the two copper centres is 2.5956?(6)?Å. O-H?O and N-H?O hydrogen bonds between the complex cation, the water mol-ecule and the sulfate anion lead to the formation of a three-dimensional network.

SUBMITTER: Zhang X 

PROVIDER: S-EPMC2972028 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature