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Diazido-bis(2,2'-biimidazole)manganese(II).

ABSTRACT: In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry ) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa-hedral MnN(6) geometry for the metal ion. In the crystal structure, N-H⋯N hydrogen bonds help to consolidate the packing.

SUBMITTER: Zhang X

PROVIDER: S-EPMC2961868 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Diazido-bis(2,2'-biimidazole)manganese(II).

Zhang Xiutang X Wei Peihai P Li Bin B

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry ) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa-hedral MnN(6) geometry for the metal ion. In the crystal structure, N-H⋯N hydrogen bonds help to consolidate the packing. ...[more]

PMID: 21202788

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