Browse
Submit Data
Databases
API
Help

Dataset Information

3 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tetra-kis(1,2-dimethoxy-ethane-κO,O')ytterbium(II) bis-(μ(2)-phenyl-selenolato-κSe:Se)bis-[bis-(phenyl-selenolato-κSe)mercurate(II)].

ABSTRACT: The title salt, [Yb(C(4)H(10)O(2))(4)][Hg(2)(C(6)H(5)Se)(6)], consists of eight-coordinate homoleptic [Yb(DME)(4)](2+) dications (DME is 1,2-dimethoxy-ethane) countered with [Hg(2)(SePh)(6)](2-) di-anions. The cations and anions have twofold rotation and inversion symmetry, respectively. The Yb centre displays a square-anti-prismatic coordination geometry and the Hg centre has a distorted tetra-hedral coordination environment. One phenyl-selenolate anion and one methyl group of a DME ligand are disordered over two positions with equal occupancies. This structure is unique in that it represents a less common mol-ecular lanthanide species in which the lanthanide ion is not directly bonded to an anionic ligand. There are no occurrences of the [Hg(2)(SePh)(6)](2-) dianion in the Cambridge Structural Database (Version of November 2007), but there are similar oligomeric and polymeric Hg(x)(SePh)(y) species. The crystal structure is characterized by alternating layers of cations and anions stacked along the c axis.

SUBMITTER: Romanelli MD

PROVIDER: S-EPMC2961915 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Tetra-kis(μ(2)-3,4-dimethoxy-phenyl-acetato)-κO,O':O';κO:O:O';κO:O';κO:O'-bis-[(3,4-dimethoxy-phenyl-acetato-κO,O')(1,10-phenanthroline-κN,N)thulium(III)].

Project description:In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging and bridging tridentate modes.

| S-EPMC2979998 | biostudies-literature

Tetra-kis(?-3,4-dimethoxy-phenyl-acetato)bis-[(3,4-dimethoxy-phenyl-acetato)(1,10-phenanthroline)dysprosium(III)].

Project description:The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxy-phenylacetate (L) anions, two 1,10-phenanthroline (phen) mol-ecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol-ecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C-H?O hydrogen bonding interactions consolidate the crystal packing.

| S-EPMC2983715 | biostudies-literature

Di-?-chlorido-bis-[chlorido(dimethoxy-phenyl-phosphine)palladium(II)].

Project description:The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd?Pd distance of 3.4662?(17)?Å. It has a similar geometry to that observed in the triphenyl-phosphite and triphenyl-phosphine analogues. The Pd-P bond length is ca 0.04?Å shorter than those in mononuclear PdCl(2)(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl(-) compared to a single-bonded Cl(-) atom.

| S-EPMC2979266 | biostudies-literature

(?-Ethane-1,2-diamine-?N:N')bis-[bis-(ethane-1,2-diamine-?N,N')zinc(II)] tetra-kis-(perchlorate).

Project description:In the title salt, [Zn(2)(C(2)H(8)N(2))(5)](ClO(4))(4), an ethyl-enediamine mol-ecule bridges two bis-(ethyl-enediamine)-zinc units; the five-coordinate Zn atoms show a trigonal-bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation inter-acts weakly with the anion by N-H?O hydrogen bonds, generating a three-dimensional network.

| S-EPMC3009181 | biostudies-literature

Tetra-kis(μ-penta-fluoro-benzoato-κO:O')bis-[(tetra-hydro-furan-κO)molybdenum(II)].

Project description:In the asymmetric unit of the title compound, [Mo(2)(C(7)F(5)O(2))(4)(C(4)H(8)O)(2)], two independent half-mol-ecules are present, which are completed by a crystallographically imposed center of inversion between the individual Mo atoms. In each mol-ecule, four penta-fluoro-benzoate anions bridge the quadruply bonded Mo(2) (4+) unit that is, in addition, axially coordinated by two O atoms of tetra-hydro-furan (THF) mol-ecules. In the two independent mol-ecules, the mean Mo-Mo bond length is 2.110 Å. Since the THF mol-ecules are equally disordered over two sets of sites, there are four different Mo-O distances in both half-mol-ecules with an overall mean of 2.542 Å. A zigzag chain is formed by π-π stacking inter-actions between penta-fluoro-phenyl rings, indicated by a centroid-centroid distance of 3.7054 (11) Å and a centroid-to-plane distance of 3.4169 (3) Å. The extension of the unit gives a three-dimensional network structure with the THF mol-ecules located in the voids.

| S-EPMC3200930 | biostudies-literature

1,1,2,2-Tetra-kis(dimethyl-amino)-ethane-1,2-diium bis-(tetra-phenyl-borate) acetone disolvate.

Project description:The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C-C single bond by 63.8?(3)° and the positive charges are delocalized over both N-C-N planes.

| S-EPMC3344502 | biostudies-literature

Crystal structure of bis(μ2-tri-phenyl-acetato-κO:κO')bis(diisobutylaluminium).

Project description:Single crystals of the title compound, [Al(iBu)2(O2CCPh3)]2 or [Al2(C4H9)4(C20H15O2)2], have been formed in the reaction between tris-(tetra-hydro-furan)-tris-(tri-phenyl-acetato)-neodymium, [Nd(Ph3CCOO)3(THF)3], and triiso-butyl-aluminium, Al(iBu)3, in hexane followed by low-temperature crystallization (243 K) from the reaction mixture. The structure has triclinic (P ) symmetry at 120 K. The dimeric complex [Al(iBu)2(O2CCPh3-μ-κO:κO')]2 is located about an inversion centre. The tri-phenyl-acetate ligand displays a μ-κO:κO'-bridging coordination mode, leading to the formation of an octa-gonal Al2O4C2 core. The complex displays HPh⋯CPh inter-molecular inter-actions.

| S-EPMC6509680 | biostudies-other

Bis(μ-N-nitroso-N-phenyl-hydroxy-laminato)-κO,O':O';κO':O,O'-bis-[(N-nitroso-N-phenyl-hydroxy-laminato-κO,O')lead(II)].

Project description:The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa-hedral; if another two longer inter-molecular Pb⋯O inter-actions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square anti-prism.

| S-EPMC3052047 | biostudies-literature

Bis(N-phenyl-ethane-1,2-diamine)dithio-cyanato-nickel(II).

Project description:The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol-ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl-ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio-cyanate ligands, giving a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (100) by N-H?S inter-actions.

| S-EPMC2979796 | biostudies-literature

Crystal structure of tetra-kis-(tetra-hydro-furan-κO)bis-(tri-fluoro-methane-sulfonato-κO)iron(II).

Project description:The title compound, [Fe(CF3SO3)2(C4H8O)4], is octa-hedral with two tri-fluoro-methane-sulfonate ligands in trans positions and four tetra-hydro-furane mol-ecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enanti-omerically pure. The packing of the mol-ecules is determined by weak C-H⋯O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.

| S-EPMC6775732 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data