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Methyl N'-[(E)-4-hydr-oxy-3-methoxy-benzyl-idene]hydrazinecarboxyl-ate.

ABSTRACT: The mol-ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 36.54?(6)°. The mol-ecules are linked into a two-dimensional network by inter-molecular O-H?O, N-H?O and O-H?N hydrogen bonds, and by aromatic ?-? stacking inter-actions [ring-centroid separation 3.7689?(9)?Å].

SUBMITTER: Cheng XW 

PROVIDER: S-EPMC2962030 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Methyl N'-[(E)-4-hydr-oxy-3-methoxy-benzyl-idene]hydrazinecarboxyl-ate.

Cheng Xiang-Wei XW  

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

The mol-ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 36.54 (6)°. The mol-ecules are linked into a two-dimensional network by inter-molecular O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonds, and by aromatic π-π stacking inter-actions [ring-centroid separation 3.7689 (9) Å]. ...[more]

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