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(E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.

ABSTRACT: The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol-ecule are essentially coplanar, with a maximum deviation of 0.015?(2)?Å. An intra-molecular O-H?N inter-action is observed. In the crystal structure, the mol-ecules are linked into a two-dimensional network parallel to the ac plane by N-H?O hydrogen bonds involving the meth-oxy O atom and by two C-H?O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C-H?? inter-action is observed.

SUBMITTER: Lv LP

PROVIDER: S-EPMC2969457 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.

Lv Lu-Ping LP Yu Wen-Bo WB Li Wei-Wei WW Zhang Yong-Zhao YZ Hu Xian-Chao XC

Acta crystallographica. Section E, Structure reports online 20090610 Pt 7

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol-ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra-molecular O-H⋯N inter-action is observed. In the crystal structure, the mol-ecules are linked into a two-dimensional network parallel to the ac plane by N-H⋯O hydrogen bonds involving the meth-oxy O atom and by two C-H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an in ...[more]

PMID: 21582834

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