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Methyl 2-[(E)-3-hydr-oxy-4-methoxy-benzyl-idene]hydrazinecarboxyl-ate.

ABSTRACT: The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxyl-ate group is twisted from the benzene ring by 6.62?(5)° and an intramolecular O-H?O hydrogen bond occurs. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to (100) by O-H?O, N-H?O and C-H?O hydrogen bonds. In addition, weak C-H?? inter-actions are observed.

SUBMITTER: Lv LP

PROVIDER: S-EPMC2969549 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Methyl 2-[(E)-3-hydr-oxy-4-methoxy-benzyl-idene]hydrazinecarboxyl-ate.

Lv Lu-Ping LP Yu Tie-Ming TM Yu Wen-Bo WB Li Wei-Wei WW Hu Xian-Chao XC

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxyl-ate group is twisted from the benzene ring by 6.62 (5)° and an intramolecular O-H⋯O hydrogen bond occurs. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to (100) by O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds. In addition, weak C-H⋯π inter-actions are observed. ...[more]

PMID: 21583232

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(E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.

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