Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{2-[1-(2-Amino-2-methyl-propyl-imino)eth-yl]phenolato-?N,N',O}dioxidovanadium(V).

ABSTRACT: In the crystal structure of the title compound, [V(C(12)H(17)N(2)O)O(2)], the vanadium(V) centre is five-coordinate in a distorted square-pyramidal environment. The three atoms of the deprotonated Schiff base and a double-bonded O atom comprise the basal plane. N-H?O hydrogen bonds lead to a zigzag chain structure parallel to [001].

SUBMITTER: Romanowski G

PROVIDER: S-EPMC2968252 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

{2-[1-(2-Amino-2-methyl-propyl-imino)eth-yl]phenolato-κN,N',O}dioxidovanadium(V).

Romanowski Grzegorz G Wera Michał M Sikorski Artur A

Acta crystallographica. Section E, Structure reports online 20090114 Pt 2

In the crystal structure of the title compound, [V(C(12)H(17)N(2)O)O(2)], the vanadium(V) centre is five-coordinate in a distorted square-pyramidal environment. The three atoms of the deprotonated Schiff base and a double-bonded O atom comprise the basal plane. N-H⋯O hydrogen bonds lead to a zigzag chain structure parallel to [001]. ...[more]

PMID: 21581791

Similar Datasets

Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

Project description:The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H?O hydrogen bonds.

| S-EPMC2961174 | biostudies-literature

Bis{?-2-[1-(pyridin-2-yl-methyl-imino)-eth-yl]phenolato}bis-(azido-zinc).

Project description:The title compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], is a phenolate-bridged centrosymmetric dinuclear zinc(II) complex. The Zn?Zn distance is 3.076?(1)?Å. Each Zn atom is five-coordinated by two O and two N atoms from two Schiff base ligands, and by one azide N atom, forming a square-pyramidal geometry.

| S-EPMC3247522 | biostudies-literature

(2-{[2-(2-Amino-ethyl-amino)-eth-yl]imino-meth-yl}phenolato)nickel(II) chloride dihydrate.

Project description:In the title complex, [Ni(C(11)H(16)N(3)O)]Cl·2H(2)O, the Ni(II) ion is coordinated within a distorted square-planar environment. In the crystal, inter-molecular N-H?Cl, N-H?O, O-H?O, O-H?Cl and weak C-H?O hydrogen bonds link the components into a two-dimensional network parallel to (001).

| S-EPMC3050410 | biostudies-literature

Bis{2,4-dichloro-6-[3-(dimethyl-amino)propyl-imino-meth-yl]phenolato}copper(II).

Project description:In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.

| S-EPMC2970479 | biostudies-literature

{4-Chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}{4-chloro-2-[(2-oxido-eth-yl)imino-meth-yl]phenolato}cobalt(III).

Project description:In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H?O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638?(3):0.362?(3) ratio.

| S-EPMC3008055 | biostudies-literature

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-dihydro-seleno-phenolato}zinc(II).

Project description:In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.

| S-EPMC2969977 | biostudies-literature

Chlorido{?-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-?-oxido-dicopper(II) trihydrate.

Project description:In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H?Cl hydrogen bonds while O-H?O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

| S-EPMC3379123 | biostudies-literature

Tris[2-(propyl-imino-meth-yl)phenolato-?N,O]cobalt(III).

Project description:The title compound, [Co(C(10)H(12)NO)(3)], was synthesized from cobalt(III) fluoride and 2-(propyl-imino-meth-yl)phenol in refluxing methanol. The Co(III) ion is hexa-coordinated by three N and three O atoms from three bidentate Schiff base ligands in an octa-hedral geometry.

| S-EPMC2961544 | biostudies-literature

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

Project description:The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

| S-EPMC2961833 | biostudies-literature

Di-?(1,1)-azido-bis-[(2-{1-[2-(isopropyl-amino)ethyl-imino]eth-yl}phenolato)copper(II)].

Project description:In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu?Cu separation is 3.2365?(3)?Å. A pair of intra-molecular N-H?O hydrogen bonds helps to establish the mol-ecular conformation.

| S-EPMC2979365 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data