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Catena-Poly[[trimethyl-tin(IV)]-?-cyclo-hex-3-ene-1-carboxyl-ato].

ABSTRACT: The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H?O hydrogen bond.

SUBMITTER: Ren Y

PROVIDER: S-EPMC2980015 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyl-tin(IV)]-μ-cyclo-hex-3-ene-1-carboxyl-ato].

Ren Yun Y Zhang Rufen R Shi Yang Y

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H⋯O hydrogen bond. ...[more]

PMID: 21579982

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