Browse
Submit Data
Databases
API
Help

Dataset Information

22 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichloridobis(5,7-dichloro-quinolin-8-olato-?N,O)tin(IV).

ABSTRACT: The Sn(IV) atom in the title compound, [Sn(C(9)H(4)Cl(2)NO)(2)Cl(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the Cl atoms; the O atoms are trans to each other.

SUBMITTER: Fazaeli Y

PROVIDER: S-EPMC2968467 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichloridobis(5,7-dichloro-quinolin-8-olato-κN,O)tin(IV).

Fazaeli Yousef Y Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090213 Pt 3

The Sn(IV) atom in the title compound, [Sn(C(9)H(4)Cl(2)NO)(2)Cl(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the Cl atoms; the O atoms are trans to each other. ...[more]

PMID: 21582058

Similar Datasets

Dichloridobis(2-methyl-quinolin-8-olato-?N,O)tin(IV).

Project description:The bis-chelated Sn atom in the title compound, [Sn(C(10)H(8)NO)(2)Cl(2)], exists in a distorted cis-Cl(2),cis-N(2),trans-O(2) octa-hedral environment.

| S-EPMC2969261 | biostudies-literature

Benzyl-chloridobis(quinolin-8-olato)tin(IV).

Project description:In the title compound, [Sn(C(7)H(7))(C(9)H(6)NO)(2)Cl], the Sn(IV) ion is in a distorted octa-hedral coordination environment formed by the O and N atoms of two bis-chelating quinolin-8-olate ligands, a Cl atom and a C atom from a benzyl ligand. The axial sites are occupied by an N atom of a quinolinate ligand and the C atom of the benzyl ligand. The axial Sn-N bond is slightly shorter than the equatorial Sn-N bond.

| S-EPMC2977110 | biostudies-literature

Chloridometh-yl(2-methyl-quinolin-8-olato-?N,O)phenyl-tin(IV).

Project description:The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82?(8) and 137.69?(8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn?Cl distance of 3.595?(1)?Å. Weak inter-molecular C-H?O and C-H?Cl hydrogen bonding is present in the crystal structure.

| S-EPMC3007514 | biostudies-literature

Chloridobis(2-chloro-benz-yl)(quinolin-8-olato-?N,O)tin(IV).

Project description:The Sn(IV) atom in the three independent mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)(C(9)H(6)NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C(2)SnNOCl trigonal-bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.

| S-EPMC3120540 | biostudies-literature

Dimethyl-bis-(2-methyl-quinolin-8-olato-?(2) N,O)tin(IV).

Project description:The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91?(18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6?(2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H?O hydrogen bonding occurs in the crystal.

| S-EPMC3588791 | biostudies-literature

Tetra-kis(5,7-dimethyl-quinolin-8-olato-?N,O)hafnium(IV) dimethyl-formamide disolvate.

Project description:In the title compound, [Hf(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Hf(IV) atom is coordinated by four N,O-donating bidentate 5,7-dimethyl-8-quinolino-late (Ox(-)) ligands arranged to give a distorted square-anti-prismatic coordination polyhedron. The average Hf-O and Hf-N distances are 2.098 and 2.298?Å, respectively, and the average O-Hf-N bite angle is 70.2°. The crystal packing is controlled by ?-? inter-actions between Ox(-) ligands of neighbouring mol-ecules, giving rise to a three-dimensional supra-molecular grid network. The inter-planar distances vary from 3.441?(1) to 3.509?(1)?Å, while the centroid-centroid distances vary from 3.688?(2) to 3.759?(12)?Å. A non-classical C-H?O hydrogen bond is observed between the complex and one of the solvate mol-ecules.

| S-EPMC3201287 | biostudies-literature

Bis(?-quinolin-8-olato)-?N,O:O;?O:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

Project description:The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83?(8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H?Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100].

| S-EPMC3007587 | biostudies-literature

5,7-Dichloro-quinolin-8-ol.

Project description:The mol-ecule of the title compound, C(9)H(5)Cl(2)NO, is essentially planar [give maximum or r.m.s. deviation] and the hydr-oxy group acts as a hydrogen-bond donor to the N atom of a symmetry-related mol-ecule, generating a hydrogen-bonded dimer,which lies on a twofold rotation axis.

| S-EPMC2977804 | biostudies-other

Dichloridobis(2-chloro-benz-yl)tin(IV).

Project description:Mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)], lie on a twofold rotation axis which passes through the Sn atom. The Sn(IV) atom exists in a distorted tetra-hedral geometry. Adjacent mol-ecules are linked by weak Sn?Cl contacts [3.703?(1)?Å], forming a linear chain motif extending along the b axis.

| S-EPMC3007463 | biostudies-literature

(2-Methyl-quinolin-8-olato-?N,O)di-phenyl-(thio-cyanato-?N)tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(10)H(8)NO)(NCS)], is chelated by the 2-methyl-quinolin-8-olate anion and is five-coordinate in a trigonal-bipramidal geometry [C-Sn-C = 133.47?(13) and 138.77?(12)°]. There are two independent mol-ecules of similar conformation in the asymmetric unit.

| S-EPMC2979818 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data