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Chloridometh-yl(2-methyl-quinolin-8-olato-?N,O)phenyl-tin(IV).

ABSTRACT: The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82?(8) and 137.69?(8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn?Cl distance of 3.595?(1)?Å. Weak inter-molecular C-H?O and C-H?Cl hydrogen bonding is present in the crystal structure.

SUBMITTER: Vafaee M 

PROVIDER: S-EPMC3007514 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Chloridometh-yl(2-methyl-quinolin-8-olato-κN,O)phenyl-tin(IV).

Vafaee Maryam M   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonding is prese  ...[more]

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