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Trans-Bis(4-methoxy-thio-phenolato-κS)bis-(trimethyl-phosphine-κP)nickel(II).

ABSTRACT: The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy-thio-phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio-phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.

SUBMITTER: Cao R 

PROVIDER: S-EPMC2960343 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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trans-Bis(4-methoxy-thio-phenolato-κS)bis-(trimethyl-phosphine-κP)nickel(II).

Cao Ruixia R   Wang Qibao Q   Sun Hongjian H  

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy-thio-phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio-phenolate ligands are almost perpendicular to the square coordination p  ...[more]

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