Unknown

Dataset Information

0

Bis(?-2-methyl-quinolin-8-olato)-?N,O:O;?O:N,O-bis-[(methanol-?O)(nitrato-?O,O')lead(II)].


ABSTRACT: The mol-ecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb?O inter-action is considered, the geometry approximates a ?-cube in which one of the sites is occupied by a stereochemically active lone pair.

SUBMITTER: Mohammadnezhad Sh G 

PROVIDER: S-EPMC2968636 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

Bis(μ-2-methyl-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[(methanol-κO)(nitrato-κO,O')lead(II)].

Mohammadnezhad Sh Gholamhossein G   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20090211 Pt 3


The mol-ecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb⋯O inter-action is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair. ...[more]

Similar Datasets

| S-EPMC2979204 | biostudies-literature
| S-EPMC2969373 | biostudies-literature
| S-EPMC2977601 | biostudies-literature
| S-EPMC2983420 | biostudies-literature
| S-EPMC2977600 | biostudies-literature
| S-EPMC2968542 | biostudies-other
| S-EPMC2968633 | biostudies-literature
| S-EPMC2983236 | biostudies-literature
| S-EPMC2960138 | biostudies-literature
| S-EPMC2961573 | biostudies-literature