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Dichlorido[2,2'-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II).

ABSTRACT: In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O-H?O and O-H?Cl hydrogen bonds involving hydr-oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a ?-? stacking inter-action between adjacent 1,10-phenanthroline rings, with a distance of 3.675?(2)?Å between the centroids of the pyridine and benzene rings.

SUBMITTER: Zhang SG

PROVIDER: S-EPMC2970345 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Dichlorido[2,2'-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II).

Zhang Shi Guo SG Xie Long Miao LM

Acta crystallographica. Section E, Structure reports online 20090919 Pt 10

In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O-H⋯O and O-H⋯Cl hydrogen bonds involving hydr-oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π-π stacking inter-action between adjacent 1,10-phenanthroline rings, with a distance of 3.675 (2) Å between the centroids of the pyridine and benzene rings. ...[more]

PMID: 21577753

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