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(2-Amido-3-oxidopyridinium-?N,O)dibenzyl-chloridotin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(7)H(7))(2)(C(5)H(5)N(2)O)Cl], shows a distorted C(2)ClNOSn trigonal-bipyramidal coordin-ation, with a Cl-Sn-O axial angle of 163.77?(3)°, but the C-Sn-C angle [141.43?(7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N-H(pyridinium)?O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell.

SUBMITTER: Tan CL

PROVIDER: S-EPMC2969204 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(2-Amido-3-oxidopyridinium-κN,O)dibenzyl-chloridotin(IV).

Tan Chui Lian CL Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The Sn atom in the title compound, [Sn(C(7)H(7))(2)(C(5)H(5)N(2)O)Cl], shows a distorted C(2)ClNOSn trigonal-bipyramidal coordin-ation, with a Cl-Sn-O axial angle of 163.77 (3)°, but the C-Sn-C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N-H(pyridinium)⋯O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell. ...[more]

PMID: 21582665

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