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Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

ABSTRACT: In the title mol-ecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H?Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.

SUBMITTER: Ghallab R

PROVIDER: S-EPMC7405591 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

Ghallab Rochdi R Boutebdja Mehdi M Dénès George G Merazig Hocine H

Acta crystallographica. Section E, Crystallographic communications 20200717 Pt 8

In the title mol-ecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H⋯Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the c ...[more]

PMID: 32844014

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