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Bis[?(2)-N'-acetyl-2-hydroxy-6-oxido-benzohydrazidato(3-)]octa-pyridine-trinickel(II).

ABSTRACT: The title trinuclear complex, [Ni(3)(C(9)H(7)N(2)O(4))(2)(C(5)H(5)N)(8)], possesses a crystallographically imposed center of symmetry occupied by one Ni(II) ion. Each of the three Ni(II) ions is coordinated by two O and four N atoms, respectively, in a distorted octa-hedral geometry. In the crystal, weak inter-molecular C-H?? inter-actions link the mol-ecules into ribbons propagating in the [100] direction.

SUBMITTER: Yang Y

PROVIDER: S-EPMC2969366 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis[μ(2)-N'-acetyl-2-hydroxy-6-oxido-benzohydrazidato(3-)]octa-pyridine-trinickel(II).

Yang Yan Y Li Dacheng D Shi Xuefeng X

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The title trinuclear complex, [Ni(3)(C(9)H(7)N(2)O(4))(2)(C(5)H(5)N)(8)], possesses a crystallographically imposed center of symmetry occupied by one Ni(II) ion. Each of the three Ni(II) ions is coordinated by two O and four N atoms, respectively, in a distorted octa-hedral geometry. In the crystal, weak inter-molecular C-H⋯π inter-actions link the mol-ecules into ribbons propagating in the [100] direction. ...[more]

PMID: 21582684

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