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(4-Chloro-benzohydrazidato-?N',O)[2-(4-chloro-benzoyl-hydrazono-?N,O)propionato(2-)-?O]oxidovanadium(V).

ABSTRACT: In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro-benzoyl-hydrazidate anion and O,N,O'-chelated by the (chloro-benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds into a linear chain parallel to [010].

SUBMITTER: Wong HW

PROVIDER: S-EPMC2969368 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(4-Chloro-benzohydrazidato-κN',O)[2-(4-chloro-benzoyl-hydrazono-κN,O)propionato(2-)-κO]oxidovanadium(V).

Wong Hon Wee HW Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro-benzoyl-hydrazidate anion and O,N,O'-chelated by the (chloro-benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into a linear chain parallel to [010]. ...[more]

PMID: 21582662

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