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(4-Chloro-benzohydrazidato-?N',O)[2-(4-chloro-benzoyl-hydrazinyl-idene-?N,O)-3-phenyl-propionato(2-)-?O]oxidovanadium(V) methanol monosolvate.


ABSTRACT: The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H?O and O-H?O hydrogen bonds about a center of inversion, generating a dimer.

SUBMITTER: Wong HW 

PROVIDER: S-EPMC3011505 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(4-Chloro-benzohydrazidato-κN',O)[2-(4-chloro-benzoyl-hydrazinyl-idene-κN,O)-3-phenyl-propionato(2-)-κO]oxidovanadium(V) methanol monosolvate.

Wong Hon Wee HW   Lo Kong Mun KM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12


The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds about a center of inversion, generating a dimer. ...[more]

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