Ontology highlight
ABSTRACT:
SUBMITTER: Wong HW
PROVIDER: S-EPMC3011505 | biostudies-literature | 2010 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20101113 Pt 12
The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds about a center of inversion, generating a dimer. ...[more]