Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II).

ABSTRACT: In the title complex, [Pd(C(13)H(10)N(3)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half mol-ecule in which the Pd atom lies on a centre of symmetry.

SUBMITTER: Tsai CY

PROVIDER: S-EPMC2969542 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II).

Tsai Chen-Yen CY Lin Chia-Her CH Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20090507 Pt 6

In the title complex, [Pd(C(13)H(10)N(3)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half mol-ecule in which the Pd atom lies on a centre of symmetry. ...[more]

PMID: 21582989

Similar Datasets

Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyl-imino-methyl-κN)phenolato-κO]palladium(II).

Project description:In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate imine-benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-mol-ecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively.

| S-EPMC3238730 | biostudies-literature

Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl-aluminium(III)].

Project description:The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

| S-EPMC2969717 | biostudies-literature

Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN]dibromidocopper(II).

Project description:In the title complex, [CuBr(2)(C(8)H(6)N(4))(2)], the Cu(II) atom is located on an inversion centre and the asymmetric unit comprises one half-mol-ecule. The Cu atom is coordinated by two Br ions and two N atoms in approximately square-planar geometry. In the crystal structure, inter-molecular C-H⋯Br hydrogen bonds and π-π inter-actions between benzotriazole rings (centroid-centroid distance = 3.651 Å) generate a three-dimensional network.

| S-EPMC2961923 | biostudies-literature

Bis[3-(2H-benzotriazol-2-yl)-2-(prop-2-yn-yloxy)-5-(2,4,4-trimethyl-pentan-2-yl)phen-yl]methane.

Project description:In the title compound, C(47)H(54)N(6)O(2), the C-C-C bond angle between the rings is 108.40 (13)°. One aryl ring aligned at 38.5 (1)° with respect to the N-heterocyclic substituent and the other at 56.0 (1)° with respect to its substituent. In the crystal, adjacent mol-ecules are linked by C-H⋯N hydrogen bonds, forming a chain extending along the a axis.

| S-EPMC3051933 | biostudies-literature

Bis(?-trimethyl-silanolato-?O:O)bis-{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolato-?N,O]zinc}.

Project description:The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolate ligand and two bridging trimethyl-silanolate anions in a distorted tetra-hedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83?(5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858?(4):0.142?(4) and 0.665?(6):0.335?(6).

| S-EPMC3254346 | biostudies-literature

Bis[2-(1H-1,2,3-benzotriazol-1-yl)acetic acid-κN]dichloridozinc(II).

Project description:In the title complex, [ZnCl(2)(C(8)H(7)N(3)O(2))(2)], the Zn(II) atom is coordinated by two chloride ions and two N atoms in a distorted tetra-hedral coordination environment. In the crystal structure, mol-ecules are linked by inter-molecular C-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional network.

| S-EPMC2961613 | biostudies-literature

2-(2H-Benzotriazol-2-yl)-4-methyl-phenyl diphenyl-phosphinate.

Project description:In the title mol-ecule, C(25)H(20)N(3)O(2)P, the dihedral angle between the mean planes of the benzotriazol ring system and the N-bonded benzene ring is 45.8 (2)°. All but one of the angles at the P atom show slight distortions from an ideal tetra-hedral geometry.

| S-EPMC2977509 | biostudies-literature

3-(2H-Benzotriazol-2-yl)-1-(4-fluoro-phen-yl)propan-1-one.

Project description:In the title compound, C(15)H(12)FN(3)O, the benzotriazole ring system is essentially planar, with a maximum deviation from the least-squares plane of 0.016?(3)?Å. The dihedral angle between this ring system and the fluoro-substituted benzene ring is 67.97?(2)°. The crystal structure is stabilized by weak inter-molecular C-H?N inter-actions.

| S-EPMC2979255 | biostudies-literature

Bis{1-[(1H-benzotriazol-1-yl)meth-yl]-2-methyl-1H-imidazole-κN(3)}dichlorido-cobalt(II).

Project description:In the title mononuclear complex, [CoCl(2)(C(11)H(11)N(5))(2)], the Co(II) atom is four-coordinated by two ligand N atoms and two Cl atoms in a distorted tetra-hedral geometry. In the crystal, mol-ecules are stacked through π-π inter-actions [centroid-centroid distances = 3.473 (2), 3.807 (3), 3.883 (2) and 3.676 (2) Å], forming a three-dimensional supra-molecular network.

| S-EPMC3393205 | biostudies-literature

trans-Diaqua-bis{1,3-bis-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]propane}zinc(II) bis-(perchlorate).

Project description:The Zn(II) ion in the title compound, [Zn(C(15)H(14)N(10))(H(2)O)(2)](ClO(4))(2), lies on a centre of symmetry. The distorted N(4)O(2) octa-hedral coordination environment around the Zn atom is composed of two 1,3-bis-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]propane ligands (L1) and two water mol-ecules, coordinated in trans positions. The ligand acts as a typical bidentate chelating ligand through one of its 2-pyridyl-2H-tetra-zole units, forming a five-membered Zn-N-C-C-N metallacycle with a small N-Zn-N bite angle [77.40 (8)°]. The other 2-pyridyl-2H-tetra-zole unit remains uncoordinated. The average Zn-N distance (2.156 Å) is somewhat longer than the distance between the Zn(II) center and the aqua ligand [2.108 (2) Å]. The coordinated pyrid-yl-tetra-zoyl rings are quasi-coplanar, making a dihedral angle of 1.9 (2)°, while the uncoordinated rings show a larger inter-planar angle of 21.3 (2)°. The flexible propane spacer displays a zigzag chain. Inter-molecular O-H⋯N and O-H⋯O inter-actions result in two-dimensional polymeric structures parallel to (100). Two C atoms of the spacer are disordered over two positions, with site occupancy factors of ca 0.85 and 0.15.

| S-EPMC2960969 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data