Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[?-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl-aluminium(III)].

ABSTRACT: The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

SUBMITTER: Li CY

PROVIDER: S-EPMC2969717 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl-aluminium(III)].

Li Chen-Yu CY Lin Chia-Her CH Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment. ...[more]

PMID: 21583031

Similar Datasets

Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyl-imino-methyl-?N)phenolato-?O]palladium(II).

Project description:In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate imine-benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-mol-ecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831?(12) and 2.012?(2)?Å, respectively.

| S-EPMC3238730 | biostudies-literature

{2-[Bis(3-methyl-1H-indol-2-yl)meth-yl]phenolato-?O}dimeth-yl(tetra-hydro-furan-?O)aluminium(III).

Project description:The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl-aluminum in tetra-hydro-furan. The ligands adopt a distorted tetra-hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present.

| S-EPMC2971370 | biostudies-literature

Bis(?-trimethyl-silanolato-?O:O)bis-{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolato-?N,O]zinc}.

Project description:The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl-phenolate ligand and two bridging trimethyl-silanolate anions in a distorted tetra-hedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83?(5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858?(4):0.142?(4) and 0.665?(6):0.335?(6).

| S-EPMC3254346 | biostudies-literature

Bis(?-9-anthracenemethano-lato)bis-[dimethyl-aluminium(III)].

Project description:The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano-late anions. Each Al atom is tetra-coordinated by two bridging O atoms from two different 9-anthracenemethano-late ligands and by two C atoms from two methyl groups, forming a distorted tetra-hedral environment. The average Al-O bond distance in the Al(2)O(2) core is 1.845?Å.

| S-EPMC2971356 | biostudies-literature

Bis(?-4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolato)bis-[chlorido(dimethyl sulfoxide)-iron(III)] dimethyl sulfoxide disolvate.

Project description:In the centrosymmetric dimeric title complex, [Fe(2)(C(14)H(10)N(2)O(4))(2)Cl(2)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, two {Fe(L)Cl(DMSO)} units (L is the tridentate ligand 4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolate; DMSO is dimethyl sulfoxide) are bridged by two O atoms, with an Fe?Fe separation of 3.1838?(8)?Å. The coordination polyhedron of the Fe(III) atoms can be described as distorted octa-hedral, with four Fe-O, one Fe-N and one Fe-Cl coordination bonds. The L ligand is not planar, the dihedral angle between the 2-(oxidometh-yl)phen-yl]imino and 4-nitro-2-(imino-meth-yl)phenolate planes being 48.54?(9)°. The solvent DMSO molecule is disordered over two orientations with equal occupancy.

| S-EPMC3344389 | biostudies-literature

Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II).

Project description:In the title complex, [Pd(C(13)H(10)N(3)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half mol-ecule in which the Pd atom lies on a centre of symmetry.

| S-EPMC2969542 | biostudies-literature

2-(2H-Benzotriazol-2-yl)-4-methyl-phenyl diphenyl-phosphinate.

Project description:In the title mol-ecule, C(25)H(20)N(3)O(2)P, the dihedral angle between the mean planes of the benzotriazol ring system and the N-bonded benzene ring is 45.8?(2)°. All but one of the angles at the P atom show slight distortions from an ideal tetra-hedral geometry.

| S-EPMC2977509 | biostudies-literature

Bis[(1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ato-?N(3)]dichlorido-copper(II).

Project description:In the title compound, [CuCl(2)(C(12)H(15)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center and is four-coordinated in a distorted square-planar geometry by two chloride anions and two N atoms from two (1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ate ligands. The Cl-Cu-N angles of 90.55?(9) and 89.45?(9)° are close to ideal values. In the crystal, weak ?-? stacking inter-actions are observed between inversion-related benzene rings [centroid-centroid distance = 4.0028?(6)?Å].

| S-EPMC3344345 | biostudies-literature

3-(2H-Benzotriazol-2-yl)-2-hydr-oxy-5-methyl-benzaldehyde.

Project description:In the title compound, C(14)H(11)N(3)O(2), the dihedral angle between the mean planes of the benzotriazole ring system and the benzene ring of the salicylaldehyde group is 2.4?(2)°. There is an intra-molecular O-H?N hydrogen bond which may influence the mol-ecular conformation.

| S-EPMC2984053 | biostudies-literature

(1H-1,2,3-Benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ate.

Project description:In the title compound, C(12)H(15)N(3)O(2), the dihedral angle between the mean planes of the benzene and triazole rings is 0.331?(53) °. The side chain of the pivalate unit forms a dihedral angle of 69.04?(12)° with the benzotriazole unit. The ester group and two methyl groups of the pivalate unit are disordered with an occupancy ratio of 0.731?(3):0.269?(3). In the crystal, weak ?-? stacking inter-actions are observed between inversion-related benzene rings [centroid-centroid distance = 3.9040?(1)?Å].

| S-EPMC3344024 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data