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Bis[?-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl-aluminium(III)].

ABSTRACT: The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

SUBMITTER: Li CY

PROVIDER: S-EPMC2969717 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Bis[μ-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl-aluminium(III)].

Li Chen-Yu CY Lin Chia-Her CH Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The title complex, [Al(2)(CH(3))(4)(C(13)H(10)N(3)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment. ...[more]

PMID: 21583031

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