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Trans-Tetra-chloridobis(diphenyl-aceto-nitrile)platinum(IV).

ABSTRACT: In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa-hedral environment. The main geometric parameters are Pt-N = 1.960?(5)?Å, and Pt-Cl = 2.3177?(12) and 2.3196?(12)?Å. The N C bond is a typical triple bond [1.137?(7)?Å]. The Pt-N C-C unit is almost linear, with Pt-N-C and N-C-C angles of 174.6?(4) and 177.1?(6)°, respectively.

SUBMITTER: Bokach NA

PROVIDER: S-EPMC2969749 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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trans-Tetra-chloridobis(diphenyl-aceto-nitrile)platinum(IV).

Bokach Nadezhda A NA Kukushkin Vadim Yu VY Haukka Matti M

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa-hedral environment. The main geometric parameters are Pt-N = 1.960 (5) Å, and Pt-Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt-N C-C unit is almost linear, with Pt-N-C and N-C-C angles of 174.6 (4) and 177.1 (6)°, respectively. ...[more]

PMID: 21583004

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