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Trans-Tetra-aqua-bis-[2-(4-chloro-phen-oxy)acetato-?O (1)]nickel(II).

ABSTRACT: In the title compound, [Ni(C8H6ClO3)2(H2O)4], the Ni(II) ion is located on a crystallographic inversion centre and is octa-hedrally coordinated by two 2-(4-chloro-phen-oxy)acetate ligands in axial positions and by four water mol-ecules in the equatorial plane. The acetate ligands are bound to the Ni(II) ion in a monodentate manner through a carboxyl-ate O atom. In the crystal, O-H?O hydrogen bonds link the mol-ecules, forming a two-dimensional supra-molecular network lying parallel to the ab plane.

SUBMITTER: Ashurov J

PROVIDER: S-EPMC3588726 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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trans-Tetra-aqua-bis-[2-(4-chloro-phen-oxy)acetato-κO (1)]nickel(II).

Ashurov Jamshid J Ziyaev Mavlonbek M Ibragimov Bakhtiyar B Talipov Samat S

Acta crystallographica. Section E, Structure reports online 20121110 Pt 12

In the title compound, [Ni(C8H6ClO3)2(H2O)4], the Ni(II) ion is located on a crystallographic inversion centre and is octa-hedrally coordinated by two 2-(4-chloro-phen-oxy)acetate ligands in axial positions and by four water mol-ecules in the equatorial plane. The acetate ligands are bound to the Ni(II) ion in a monodentate manner through a carboxyl-ate O atom. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules, forming a two-dimensional supra-molecular network lying parallel to the ab pla ...[more]

PMID: 23468691

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