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Catena-Poly[zinc(II)-bis-[?-2-(2,4-dichloro-phen-oxy)acetato]].

ABSTRACT: The title polymeric compound, [Zn(C(8)H(5)Cl(2)O(3))(2)](n), was prepared by reaction of zinc(II) chloride with 2,4-dichloro-phenoxy-acetic acid and sodium hydroxide under hydro-thermal conditions. The Zn(II) atom is coordinated in a distorted tetra-hedral environment by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands. Each ligand bridges two Zn(II) atoms, forming a polymeric chain along the a axis. Adjacent chains are connected via C-H?Cl hydrogen bonds.

SUBMITTER: Liu SZ

PROVIDER: S-EPMC2979562 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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catena-Poly[zinc(II)-bis-[μ-2-(2,4-dichloro-phen-oxy)acetato]].

Liu Shi-Zhu SZ

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

The title polymeric compound, [Zn(C(8)H(5)Cl(2)O(3))(2)](n), was prepared by reaction of zinc(II) chloride with 2,4-dichloro-phenoxy-acetic acid and sodium hydroxide under hydro-thermal conditions. The Zn(II) atom is coordinated in a distorted tetra-hedral environment by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands. Each ligand bridges two Zn(II) atoms, forming a polymeric chain along the a axis. Adjacent chains are connected via C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21579279

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