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(Carbonato-?O,O')bis-(1,10-phenan-throline-?N,N')cobalt(III) nitrate monohydrate.

ABSTRACT: The crystal structure of the title compound, [Co(CO(3))(C(12)H(8)N(2))(2)]NO(3)·H(2)O, consists of Co(III) complex cations, nitrate anions and uncoordinated water mol-ecules. The Co(III) cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa-hedral coordination geometry. A three-dimensional supra-molecular structure is formed by O-H?O and C-H?O hydrogen bonding, C-H?? and aromatic ?-? stacking [centroid-centroid distance = 3.995?(1)Å] inter-actions.

SUBMITTER: Andac O

PROVIDER: S-EPMC2980272 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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(Carbonato-κO,O')bis-(1,10-phenan-throline-κN,N')cobalt(III) nitrate monohydrate.

Andaç Omer O Yolcu Zuhal Z Büyükgüngör Orhan O

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

The crystal structure of the title compound, [Co(CO(3))(C(12)H(8)N(2))(2)]NO(3)·H(2)O, consists of Co(III) complex cations, nitrate anions and uncoordinated water mol-ecules. The Co(III) cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa-hedral coordination geometry. A three-dimensional supra-molecular structure is formed by O-H⋯O and C-H⋯O hydrogen bonding, C-H⋯π and aromatic π-π stacking [centroid-centroid distance = 3.995 (1)Å] inter-actions. ...[more]

PMID: 21579944

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