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Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).

ABSTRACT: In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H?N and O-H?O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H?O, O-H?S, N-H?O and N-H?S hydrogen bonds, thereby forming (011) sheets.

SUBMITTER: Tai XS

PROVIDER: S-EPMC2971282 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).

Tai Xi-Shi XS Zhao Zeng-Bing ZB

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H⋯N and O-H⋯O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H⋯O, O-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, thereby forming (011) sheets. ...[more]

PMID: 21578212

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