Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).

ABSTRACT: In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H?N and O-H?O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H?O, O-H?S, N-H?O and N-H?S hydrogen bonds, thereby forming (011) sheets.

SUBMITTER: Tai XS

PROVIDER: S-EPMC2971282 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).

Tai Xi-Shi XS Zhao Zeng-Bing ZB

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H⋯N and O-H⋯O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H⋯O, O-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, thereby forming (011) sheets. ...[more]

PMID: 21578212

Similar Datasets

Tetra-aqua-bis[2-(thio-semicarbazonometh-yl)benzene-sulfonato]calcium(II).

Project description:In the title compound, [Ca(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Ca atom (site symmetry ) adopts a slightly distorted octa-hedral CaO(6) geometry and the mol-ecular conformation is stabilized by intra-molecular N-H?N inter-actions. In the crystal, the mol-ecules are linked by O-H?O, O-H?S, N-H?O and N-H?S hydrogen bonds.

| S-EPMC2970444 | biostudies-literature

Tetra-aqua-bis(pyridine-3-sulfonato-κN)nickel(II).

Project description:In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridine rings. The structure also contains inter-molecular O-H⋯O hydrogen bonding and weak C-H⋯O hydrogen bonding.

| S-EPMC2961246 | biostudies-literature

(μ-Ethane-1,1,2,2-tetra-carboxyl-ato)bis-[tetra-aqua-manganese(II)].

Project description:In the centrosymmetric title molecule, [Mn(2)(C(6)H(2)O(8))(H(2)O)(8)], the Mn(II) atom is in an octa-hedral environment coordinated by six O-atom donors from water mol-ecules and ethane-1,1,2,2-tetra-carboxyl-ate ligands. The crystal structure features a three-dimensional hydrogen-bonding network based on a strong and distinctive pattern of O-H⋯O hydrogen-bonding inter-actions.

| S-EPMC3099957 | biostudies-literature

Penta-aqua-bis[4-(2-hydroxy-benzyl-idene-amino)benzene-sulfonato]lead(II).

Project description:In the structure of the title compound, [Pb(C(13)H(10)NO(4)S)(2)(H(2)O)(5)], two S-O bonds and one C-N bond have lengths of 1.421?(9), 1.425?(8) and 1.268?(11)?Å, respectively, which suggests they are double bonds. Mol-ecules form a two-dimensional layered structure via O-H?O and O-H?N inter-actions. The Pb atom adopts distorted cubo-octahedral coordination.

| S-EPMC2968621 | biostudies-literature

Diaqua-bis-{4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonato-?(2)N,N'}nickel(II) tetra-hydrate.

Project description:In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071?(3)-2.121?(3)?Å and Ni-O = 2.071?(2) and 2.073?(3)?Å]. In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H?O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

| S-EPMC3379134 | biostudies-literature

Tetra-aqua-bis(2-oxo-1,2-dihydro-pyridine-5-sulfonato-?O)zinc(II).

Project description:The metal atom in the title compound, [Zn(C(5)H(4)NO(4)S)(2)(H(2)O)(4)], lies on a center of inversion and is linked to the anionic ligand through the carbonyl O atom. In the crystal structure, the 2-oxo-1,2-dihydro-pyridine-5-sulfon-ate ligand inter-acts with other mol-ecules through N-H?O and O-H?O hydrogen bonds, forming a three-dimensional network structure.

| S-EPMC2971040 | biostudies-literature

Tetra-aqua-bis[4-(4-pyrid-yl)pyrimidine-2-sulfonato]copper(II) dihydrate.

Project description:In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 4-(4-pyrid-yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol-ecule. The water mol-ecules, including the uncoordinated water mol-ecules, and sulfonate O atoms are involved in O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.

| S-EPMC2977545 | biostudies-literature

Bis(2-{[bis-(dimethyl-amino)-methyl-idene]amino-?N}benzene-sulfonato-?N)copper(II).

Project description:The mol-ecular structure of the title compound, [Cu(C11H16N3O3S)2], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N2O2 donor set of the two chelating 2-{[bis-(dimethyl-amino)-methyl-idene]amino}-benzene-sulfonate ligands. The Cu(II) atom lies 0.065?(1)?Å above the N2O2 plane and the Cu-O [2 × 1.945?(2)?Å] and Cu-N bond lengths [1.968?(3) and 1.962?(3)?Å] lie in expected ranges. The two aromatic ring planes make a dihedral angle of 85.48?(1)°.

| S-EPMC3588740 | biostudies-literature

Tetra-aqua-bis-[5-(pyridin-3-yl)tetra-zolido-κN⁵]manganese(II) tetra-hydrate.

Project description:The title compound, [Mn(C₆H₄N₅)₂(H₂O)₄]·4H₂O, was obtained by the solution reaction of MnCl₂ and 3-(2H-tetra-zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa-hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra-zolide ligands occupying trans positions and four water mol-ecules. In the crystal, the mononuclear complex mol-ecules and solvent water mol-ecules are connected into a three-dimensional framework by O-H⋯N and O-H⋯O hydrogen bonds.

| S-EPMC3393165 | biostudies-literature

trans-Tetra-aqua-bis-[bis-(pyridin-3-yl)methanone-?N]manganese(II) bis-(perchlorate).

Project description:In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octa-hedral coordination sphere comprising N-atom donors from two monodentate trans-related bis-(pyridin-3-yl)methanone ligands and four water ligands. The two perchlorate anions are linked to the mononuclear complex mol-ecule through water O-H?O hydrogen bonds while inter-complex water O-H?N(pyridine) inter-actions form an infinite chain structure extending along the b axis. The perchlorate anions also function as inter-unit links through water O-H?O hydrogen bonds which, together with water O-H?O(carbon-yl) inter-actions, give a three-dimensional framework structure.

| S-EPMC3254301 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data